Articles

Zn-Zn double bonds, a theoretical study

J. Echeverría, A. Falceto, S. Alvarez.
Angew. Chem. Int. Ed., 56 (2017) 10151.

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Non-existent Zn-Zn double bonds computationally predicted.

 

While double bonds are known for transition metals of groups 9 and 10, as well as for boron and p-block elements of groups 14-16, Zn sits in a small region of the periodic table with no well characterized double bonds. A qualitative reasoning indicates that zerovalent Zn has the potential for forming Zn=Zn double bonds. The computational work presented in this paper provides support for such a proposal.

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